S
- (Mariupolskyi Raion) Sopyne
- (Kramatorskyi Raion) Sofiino-Lyman
- (Kramatorskyi Raion) Samiilivka
- (Donetskyi Raion) Svistuny
- (Kalmiuskyi Raion) Samiilove
- (Kramatorskyi Raion) Starovarvarivka
- (Kramatorskyi Raion) Sosnove
- (Pokrovsk Raion) Sviatohorivka
- (Volnovakha Raion) Svobodne
- (Kalmiuskyi Raion) Svobodne
- (Donetskyi Raion) Svystuny
- (Mariupolskyi Raion) Suzhenka
- (Pokrovsk Raion) Suvorove
- (Pokrovsk Raion) Sukhi Yaly
- (Pokrovsk Raion) Sukhetske
- (Kalmiuskyi Raion) Styla
- (Horlivskyi Raion) Striukove
- (Kalmiuskyi Raion) Stroitel
- (Kalmiuskyi Raion) Strelka
- (Donetskyi Raion) Stoyany
- (Volnovakha Raion) Stepne
- (Kramatorskyi Raion) Stepanivka
- (Kramatorskyi Raion) Stepanivka
- (Horlivskyi Raion) Stepanivka
- (Mariupolskyi Raion) Stepanovka
- (Donetskyi Raion) Stepano-Krynka
- (Kramatorskyi Raion) Staryi Karavan
- (Volnovakha Raion) Staromlynivka
- (Donetskyi Raion) Staromykhailivka
- (Volnovakha Raion) Staromaiorske